有機(jī)化學(xué)實(shí)驗(yàn)（英漢雙語版）

目錄
前言
Chapter 1 General Knowledge of Organic Chemistry Experiments 1
1.1 Rules for Organic Chemistry Laboratory 1
1.2 Safety Knowledge in the Organic Laboratory 2
1.3 Commonly Used Equipment and Apparatus of Organic Chemistry Experiments 6
1.4 Cleaning and Drying of Glassware 12
1.5 Heating，Cooling and Drying of Reagents in Organic Chemistry Experiments 13
1.6 Basic Requirements for Pre-lab Work，Lab Record and Lab Report 20
Chapter 2 Basic Operations of Organic Chemistry Experiments 25
Exp.1 Determination of Melting Point 25
Exp.2 Simple Distillation and Determination of Boiling Point 29
Exp.3 Recrystallization 32
Exp.4 Extraction 38
Exp.5 Vacuum Distillation 44
Exp.6 Steam Distillation 49
Exp.7 Fractional Distillation 54
Exp.8 Column Chromatography 57
Exp.9 Thin Layer Chromatography 60
Exp.10 Paper Chromatography 64
Chapter 3 Preparation Experiments of Organic Compounds 68
Exp.11 Preparation of Cyclohexene 68
Exp.12 Preparation of 1-Bromobutane 71
Exp.13 Preparation of Bromobenzene 75
Exp.14 Preparation of 2-Methyl-2-Butanol 77
Exp.15 Preparation of Diphenylmethanol 80
Exp.16 Preparation of 1，1'-Binaphthol (a Reference-based Experiment) 82
Exp.17 Preparation of Di-n-butyl Ether 83
Exp.18 Preparation of Cyclohexanone 86
Exp.19 Preparation of Benzalacetone and Dibenzalacetone 87
Exp.20 Preparation of Benzoin 90
Exp.21 Preparation of Benzoic Acid 92
Exp.22 Preparation of Adipic Acid 94
Exp.23 Preparation of Cinnamic Acid 97
Exp.24 Preparation of Coumarin-3-carboxylic Acid 99
Exp.25 Preparation of Furfuryl Alcohol and Furoic Acid 102
Exp.26 Preparation of Ethyl Acetate 104
Exp.27 Synthesis of Dibutyl Phthalate 107
Exp.28 Synthesis of Ethyl Acetoacetate 109
Exp.29 Preparation of Acetylsalicylic Acid (Aspirin) 110
Exp.30 Preparation of Acetanilide 112
Exp.31 Preparation of p-Acetamidobenzenesulfonyl Chloride 115
Exp.32 Preparation of p-Aminobenzenesulfonamide 118
Exp.33 Green Synthesis of N-bromosuccinimide 120
Exp.34 Synthesis of Methyl Orange 121
Exp.35 The Preparation and Beckmann Rearrangement of Benzophenone Oxime 124
Exp.36 Preparation of Aniline 126
Exp.37 Preparation and Resolution of Racemic α-Phenylethylamine 129
Exp.38 Optical Resolution of Trans-1，2-diaminocyclohexane 132
Exp.39 Preparation of 2，3； 5，6-Di-O-isopropylidene-α-D-mannofuranose 134
Exp.40 Isolation of Caffeine from Tea Leaves 136
Chapter 4 Reactivity Experiments of Organic Compounds 140
Exp.41 The Preparation and Reactivities of Ethylene and Ethyne 140
Exp.42 The Reactivities of Aromatic Compounds 143
Exp.43 The Reactivities of Some Alkyl Halides 145
Exp.44 The Reactivities of Alcohols and Phenols 148
Exp.45 The Reactivities of Aldehydes and Ketones 149
Exp.46 The Reactivities of Carboxylic Acids and Their Derivatives 151
Exp.47 The Reactivities of Amines 152
第1章 有機(jī)化學(xué)實(shí)驗(yàn)的一般知識(shí) 155
1.1 有機(jī)化學(xué)實(shí)驗(yàn)室規(guī)則 155
1.2 有機(jī)化學(xué)實(shí)驗(yàn)室的安全知識(shí) 155
1.3 有機(jī)化學(xué)實(shí)驗(yàn)常用儀器和裝置 158
1.4 玻璃儀器的洗滌和干燥 163
1.5 有機(jī)化學(xué)實(shí)驗(yàn)中試劑的加熱、冷卻和干燥 165
1.6 實(shí)驗(yàn)預(yù)習(xí)、實(shí)驗(yàn)記錄和實(shí)驗(yàn)報(bào)告的基本要求 169
第2章 有機(jī)化學(xué)實(shí)驗(yàn)基本操作 174
實(shí)驗(yàn)1 熔點(diǎn)測定 174
實(shí)驗(yàn)2 簡單蒸餾及沸點(diǎn)測定 177
實(shí)驗(yàn)3 重結(jié)晶 180
實(shí)驗(yàn)4 萃取 184
實(shí)驗(yàn)5 減壓蒸餾 188
實(shí)驗(yàn)6 水蒸氣蒸餾 192
實(shí)驗(yàn)7 分餾 196
實(shí)驗(yàn)8 柱色譜 198
實(shí)驗(yàn)9 薄層色譜 201
實(shí)驗(yàn)10 紙色譜 204
第3章 有機(jī)化合物制備實(shí)驗(yàn) 207
實(shí)驗(yàn)11 環(huán)己烯的制備 207
實(shí)驗(yàn)12 1-溴丁烷的制備 210
實(shí)驗(yàn)13 溴苯的制備 212
實(shí)驗(yàn)14 2-甲基-2-丁醇的制備 215
實(shí)驗(yàn)15 二苯甲醇的制備 217
實(shí)驗(yàn)16 1，1'-聯(lián)二萘酚的合成(文獻(xiàn)實(shí)驗(yàn)) 218
實(shí)驗(yàn)17 正丁醚的制備 219
實(shí)驗(yàn)18 環(huán)己酮的制備 221
實(shí)驗(yàn)19 芐叉丙酮和二芐叉丙酮的制備 222
實(shí)驗(yàn)20 安息香的制備 224
實(shí)驗(yàn)21 苯甲酸的制備 226
實(shí)驗(yàn)22 己二酸的制備 228
實(shí)驗(yàn)23 肉桂酸的制備 229
實(shí)驗(yàn)24 香豆素-3-羧酸的制備 232
實(shí)驗(yàn)25 呋喃甲醇和呋喃甲酸的制備 234
實(shí)驗(yàn)26 乙酸乙酯的制備 236
實(shí)驗(yàn)27 鄰苯二甲酸二丁酯的制備 238
實(shí)驗(yàn)28 乙酰乙酸乙酯的制備 240
實(shí)驗(yàn)29 乙酰水楊酸(阿司匹林)的制備 241
實(shí)驗(yàn)30 乙酰苯胺的制備 242
實(shí)驗(yàn)31 對(duì)乙酰氨基苯磺酰氯的制備 245
實(shí)驗(yàn)32 對(duì)氨基苯磺酰胺的制備 247
實(shí)驗(yàn)33 N-溴代丁二酰亞胺的綠色合成 248
實(shí)驗(yàn)34 甲基橙的制備 250
實(shí)驗(yàn)35 二苯甲酮肟的制備及貝克曼重排 252
實(shí)驗(yàn)36 苯胺的制備 253
實(shí)驗(yàn)37 外消旋α-苯乙胺的制備和拆分 255
實(shí)驗(yàn)38 反-1，2-二氨基環(huán)己烷的手性拆分 258
實(shí)驗(yàn)39 2，3；5，6-二-O-異丙叉基-α-D-呋喃甘露糖的制備 259
實(shí)驗(yàn)40 從茶葉中提取咖啡因 261
第4章 有機(jī)化合物性質(zhì)實(shí)驗(yàn) 264
實(shí)驗(yàn)41 乙烯、乙炔的制備和性質(zhì) 264
實(shí)驗(yàn)42 芳烴的性質(zhì) 266
實(shí)驗(yàn)43 鹵代烴的性質(zhì) 268
實(shí)驗(yàn)44 醇和酚的性質(zhì) 270
實(shí)驗(yàn)45 醛和酮的性質(zhì) 271
實(shí)驗(yàn)46 羧酸及其衍生物的性質(zhì) 272
實(shí)驗(yàn)47 胺的性質(zhì) 273
參考文獻(xiàn) 276